[quote]veruvius wrote:
dollarbill44 wrote:
Correct me if I’m wrong (which I probably am), but the energy used for the evaporation of water off the surface of the skin would not be expended by your body, rather through an energy transfer in the atmosphere, because the evaporation of water is the dispersion of the water into the air.
You’re also assuming that the body would use stored fat first to fuel the evaporation process, which is not necessarily the case, no?
A more foolproof idea would be to just boil away the fat through the application of intense heat to the skin. Literally “melting away” the fat.
DB
You’re wrong. The heat source would be your body. Air is an insulator, terrible for heat transfer (this is the idea behind down feather comforters and jackets).[/quote]
Air is an insulator but MOVING air will transfer heat very quickly. The air passing through a mid size evaporative cooler will vaporize 2 kilos of air an hour in a dry climate.
Also, just because something is a good insulator does not make it terrible for heat transfer (!?!?!). Rate of heat transfer is one thing, but so is specific heat capacity which is pretty high for air. Metal has a low specific heat capacity and heat of vaporization (not high as mentioned previously).
If you’ve ever wondered how scientists started to get those atomic mass values that set the stage for the periodic table and basically all of modern chemistry, here is step 1:
Determination of atomic masses:
In 1819, two French scientists, Pierre Dulong and Alexis Petit proposed the first direct approach to calculating atomic weights. They used laws of motion and energy from physics to posit that the amount of heat required to raise the temperature of a single atom of a solid by a given amount should be independent of the type of atom. According to Dulong and Petit, the amount of heat required to raise the temperature of 1 mole of a solid element by 1?C should be constant (although they did not formally use the term mole, rather they used gram atomic mass, which was later used to officially define the mole). Dulong and Petit’s law is usually expressed in terms of specific heat, which is the amount of heat required to raise the temperature of one gram of a substance by 1?C. In its modern form, the law says that it should require about 6 calories of heat to raise the temperature of a mole of a solid element by 1?C. In practice, Dulong and Petit’s law is far from exact, with many elements showing deviations by 10% or more. Nevertheless, it does yield good approximate values for most metals.
Here is an example:
It takes about 0.09 calories to raise 1 gram of zinc metal by 1?C. Since it should require about 6 calories to raise a mole of zinc atoms by 1?C, it can be construed that 1 gram of zinc is about 1/67 of a mole,
or that 1 mole of zinc atoms should have a mass of about 67 grams (actual value is 65.39 grams).
From these rough estimates, more precise results could then be refined by determining the volume of oxygen or chlorine that combines with the metal in a chemical reaction. This required that scientists worked out the combining ratios of atoms of different metals with atoms of oxygen and chlorine, and also the fact that a mole of oxygen or chlorine at STP had a volume of 22.4 liters.
For example, when 22.4 liters of oxygen (1 mole) is reacted with zinc, it is found that 130.78 grams of the zinc is used up. Not knowing initially that zinc atoms combines with oxygen atoms in a 1:1 molar ratio, scientists can refer to Dulong and Petit 's law to see that a mole of zinc is about 67 grams, and since oxygen is diatomic, and 1 mole of oxygen provides 2 moles of oxygen atoms, then 130.78/2 or 65.39 grams becomes the most likely choice for the exact molar and atomic mass of zinc. Knowing that oxygen accepts 2 electrons, we can also see that a zinc atom has a valence of 2 (donates 2 electrons in ionic bonding). From this, the masses and valence electrons of other elements could be built up. 40.08 grams of calcium combines with 22.4 Liters of oxygen-the atomic mass of calcium is 40.08. 40.47 grams of aluminum combines with 22.4 liters of oxygen, but aluminum’s atomic mass is closer to 27 from Dulong and Petit 's law, so it is assumed that aluminum combines 2:3 with atoms of oxygen, or 1:3 with molecules of O2 and therefore the valence of aluminum is 3 and the molar mass is 2/3 x 40.47 or 26.98 grams/mole.